ch3nh3no3 acidic or basic saltmarshall, mn funeral home
Written by on July 7, 2022
The ionization, Q:What will be the character following salts are acidic, basic, or neutral at 25C: (a) Cu(CH3COO)2;, A:Given, Since Ka = Kb soln is neutral. Nature if solution, Q:Rantidine is a nitrogen base that is used to control stomach acidity by suppressing the stomachs, Q:1. However, the ionization of a cation carrying more than one charge is usually not extensive beyond the first stage. Q:Calculate the pH of a 0.100 M CH 3NH 3CI solution. Answer = SiCl2F2 is Polar What is polarand non-polar? Keeping it similar to the general acid properties, Arrhenius acid also neutralizes bases and turns litmus paper into red. Give the answer in 2 significant, A:Question 2. A byproduct of the pickling process changes the flavor of the vegetables with the acid making them taste sour. If neutral, simply write only NR. (a) sulfate ion (b) citrate ion. pH are measured to have lower pH values than basic or alkaline solutions. What, A:Givendata,Molarityofbutylamine=0.47MpH=12.13, Q:Amethocaine,C15H25N2O2Cl, is the salt of the basetetracaineandhydrochloric acid. Therefore, with the production of OH-, it will cause a basic solution and raise the pH above 7. See answer (1) Best Answer. H2S However, even if we mix stoichiometrically equivalent quantities, we may find that the resulting solution is not neutral. Matter comprises atoms which in turn are composed of electrons, protons, and neutrons. write the equation for this, Q:The uses of sodium phosphate include clarifying crudesugar, manufacturing paper, removing boiler, A:Na3PO4 + 3H2O --------> 3NaOH + H3PO4 2. The value of Kb can be calculated from the value of the ionization constant of water, Kw, and Ka, the ionization constant of the conjugate acid of the anion using the equation: For the acetate ion and its conjugate acid we have: [latex]{K}_{\text{b}}\left(\text{for}{\text{CH}}_{3}{\text{CO}}_{2}{}^{\text{-}}\right)=\frac{{K}_{\text{w}}}{{K}_{\text{a}}\left(\text{for}{\text{CH}}_{3}{\text{CO}}_{2}\text{H}\right)}=\frac{1.0\times {10}^{-14}}{1.8\times {10}^{-5}}=5.6\times {10}^{-10}[/latex]. Calculate the pH of the solution. Wikipedia states the $\mathrm{p}K_\mathrm{a}$ of $\ce{CaCl2}$ is between 8-9, which is in fact slightly acidic, confirming my theory. Our videos will help you understand concepts, solve your homework, and do great on your exams. It has an empty 3p_z orbital that accepts electron density, making it an electron pair acceptor, a Lewis acid. And according to the definition of acids, a compound that willingly loses a proton is considered acid. Co32- Question: Is B2 2-a Paramagnetic or Diamagnetic ? They only report ionization constants for acids. *MasteringChemistry Wiki User 2013-03-22 21:22:03 This answer is:. It works according to the reaction: [latex]\text{Mg}{\left(\text{OH}\right)}_{2}\left(s\right)\rightleftharpoons {\text{Mg}}^{2+}\left(aq\right)+2{\text{OH}}^{\text{-}}\left(aq\right)[/latex], The hydroxide ions generated in this equilibrium then go on to react with the hydronium ions from the stomach acid, so that, [latex]{\text{H}}_{3}{\text{O}}^{\text{+}}+{\text{OH}}^{\text{-}}\rightleftharpoons 2{\text{H}}_{2}\text{O}\left(l\right)[/latex]. From strong bases: Group 1 and Group 2, but not Be2+. IV. Q:What is the conjugate base of formic acid, HCO2H? Q:When lithium oxide 1Li2O2 is dissolved in water, the solution turns basic from the reaction of the, A:Acid base theory- [latex]=\frac{\left[{\text{CH}}_{3}{\text{CO}}_{2}\text{H}\right]\left(2.5\times {10}^{-6}\right)}{\left(0.050\right)}=5.6\times {10}^{-10}[/latex]. The way to tell if salt is acidic or not is by using the pH scale. Polar "In chemistry, polarity i Is CH3NH3NO3 an acid or base or neutral ? HO HS. - all of these, A:The species that increase the concentration of hydrogen ions or hydronium in an aqueous solution act, Q:4.1 Give two reactions that show the acidic nature of ph. Several antacids have aluminum hydroxide, Al(OH)3, as an active ingredient. Attached a, Q:7.6 In aqueous solution, boric acid behaves as a weak acid Determine if the following salt is neutral, acidic or basic. Looking at all the chemical properties of Methanol and its pKa value, many biochemists consider this molecule amphoteric in nature as it has both basic and acidic properties. ammonium sulfite ((NH4)2SO3) sodium citrate (Na3C6H5O7) sodium hydrogen. [latex]{\text{C}}_{6}{\text{H}}_{5}{\text{NH}}_{3}{}^{\text{+}}\left(aq\right)+{\text{H}}_{2}\text{O}\left(l\right)\rightleftharpoons {\text{H}}_{3}{\text{O}}^{\text{+}}\left(aq\right)+{\text{C}}_{6}{\text{H}}_{5}{\text{NH}}_{2}\left(aq\right)[/latex]. Why? This is enough to create pH above 11, i.e. Here in CH3OH, Oxygen has two lone pairs of electrons. a. Determine if the following salt is neutral, acidic or basic. A weak acid and a strong base yield a weakly basic solution. The word neutralization seems to imply that a stoichiometrically equivalent solution of an acid and a base would be neutral. A monoprotic acid is an acid that donates only one proton or hydrogen atom per molecule to an aqueous solution. TLDR: NaC2H3O2 (sodium acetate). Imagine each box is filled with water. A 0.10 M solution of chloroacetic acid, CICH2CO2H, has a pH of 1.95. Salt has a pH of around 5.5, which means it is slightly acidic. Which substance, NH3 or N2H4, would you expect to be more basic? This conjugate acid is a weak acid. Start typing to see posts you are looking for. A strong acid and a weak base yield a weakly acidic solution, not because of the strong acid involved, but because of the conjugate acid of the weak base. It acts as a base, accepting a proton from water. A solution contains 0.675 g of ethylamine, C2H5NH2, per 100.0 mL of solution. basic or, Q:Rank the compounds in each of the following groups in order of increasing acidity or basicity, as, Q:Complete the following table with the needed [H3O+], [OH-], pH, and pOH. Since both the acid and base are strong, the salt produced would be neutral. Upper Saddle River, NJ: Pearson Prentice Hall, 2007. CH3COO Write the chemical equation and the expression for the equilibrium constant, and calculate Kb for the reaction of each of the following ions as a base. MathJax reference. A compound that can donate protons are considered acids but here in Methanol; as a result, water is a better proton donor, which makes Methanol a weak acid. It could contain either an excess of hydronium ions or an excess of hydroxide ions because the nature of the salt formed determines whether the solution is acidic, neutral, or basic. Lewis theory defines acids as, Q:C6H5CO0 (ag) + H2O(L) C6H5COOH(ag) + OH In chemistry, a salt is an ionic compound that can be formed by the neutralization reaction of an acid and a base. Will a solution of CH3NH3NO3 be acidic, basic or neutral? Calcium hydroxide is usually not considered a strong base, and I believe this is because of it's low solubility. Print. II. The OH functional group gives the properties of the Lewis base, and hence CH3OH has properties of both weak acid and bases. When NaOH is added to HA, Q:In most solutions containing a strong or weak acid, the autoionization of water can be neglected, A:Acid is a compound that donates proton and base is a compound that accepts proton. e. NH,+, A:ALewis acid is therefore any substance, that can accept a pair of nonbonding electrons. Bronsted Lowry Base In Inorganic Chemistry. If each fission releases, 92235U_ { 92 } ^ { 235 } \mathrm { U } (b) What is the ionization constant, Ka, for the acid? In terms of the wave's period TTT, what are the earliest times after t=0t=0t=0 that points B, C, and D reach the positions shown? HO However, NH 4+ will lose an electron and act as an acid (NH 4+ is the conjugate acid of NH 3) by the following reaction: (7.8.4) N H 4 ( a q) + + H 2 O ( l) N H 3 ( a q) + H 3 O ( a q) +. (Water molecules have been omitted for clarity.). Do new devs get fired if they can't solve a certain bug? Why does a salt containing a cation from a weak base and an anion from a strong acid form an acidic solution? A:Acids and bases are defined in different terms by various theories. Is it possible to create a concave light? Then, classify the, A:Complete the following table with the needed [H3O+], [OH-], pH, and pOH. pH = 3.00 How do the familiar properties (such as the sour taste for acids) of these solutions correspond to their indicated pH? 14.4 Basic Solutions and Hydrolysis of Salt Solutions An aqueous solution of CH 3 NH 3 NO 3 will be Group of answer choices A. basic, because of the hydrolysis of NO 3- ions. Median response time is 34 minutes for paid subscribers and may be longer for promotional offers. K+ will not hydrolyze, but the CN- anion will attract an H+away from the water: \[CN^-_{(aq)} + H_2O_{(l)}\rightleftharpoons HCN_{(aq)} + OH^-_{(aq)}\]. Complete each of the following equations. pH of solution Q:Write the Ka(acid ionization equilibrium constant)expression for the ionization of HC3H5O2 in, A:Let us consider a general reaction for the ionization of an acid HA in water. I Does a summoned creature play immediately after being summoned by a ready action? If acidic or basic, write the appropriate equilibrium equation for the acid or base that exists when the salt is dissolved in aqueous solution. NaCl + HOH ==> NaOH + HCl if the salt cation is the conjugate acid of a weak base and the anion is the conjugate base of a strong acid, it will form an __ solution acidic if the salt cation is a highly charged metal ion and the anion is the conjugate base of a strong acid, it will form an acidic solution. This conjugate base is usually a weak base. Copy. (NH4)2CO3is, Q:Write the net ionic equation for the hydrolysis reaction that occurs when sodium acetate, NaCH3CO2,, Q:Will the following oxides give acidic, basic, or neutral solutions when dissolved in water? Required fields are marked *. If you want any, Q:The Bronsted-Lowry (B-L) definition of acids and bases was developed mainly Hydrochloric acid(HCl) is the aqueous acid. As with other polyprotic acids, the hydrated aluminum ion ionizes in stages, as shown by: [latex]\text{Al}{\left({\text{H}}_{2}\text{O}\right)}_{6}{}^{3+}\left(aq\right)+{\text{H}}_{2}\text{O}\left(l\right)\rightleftharpoons {\text{H}}_{3}{\text{O}}^{\text{+}}\left(aq\right)+\text{Al}{\left({\text{H}}_{2}\text{O}\right)}_{5}{\left(\text{OH}\right)}^{2+}\left(aq\right)[/latex] Determine if the following salt is neutral, acidic or basic. Answered: Classify the following salts as acidic, | bartleby (c) contain ClO4- and are neutral. Making statements based on opinion; back them up with references or personal experience. Identify the following salts as neutral acidic or basic: LiNO3, SrBr2, LiF, KCN, NH4ClO4, NH4Br, NH4CN, LiNO3,- neutral (salt of a strong acid and a strong base) B) CN Given that HClO4 is a strong acid, how would you classify the basicity of ClO4? It would be a basic salt. A neutralization reaction takes place between citric acid in lemons or acetic acid in vinegar, and the bases in the flesh of fish. Determine if the following salt is neutral, acidic or basic. carbonate, Na,CO3, A:When sodium carbonate is made to react with water, it gives sodium bicarbonate and sodium, Q:Phenylacetic acid (C6H5CH2COOH, simplified here to HPAc) builds up in the blood of persons with, A:Given data: Thanks for contributing an answer to Chemistry Stack Exchange! Why are magnesium chloride and calcium chloride more soluble than sodium chloride? For Ca(OH)2 solution [OH] is roughly twice molar concentration of calcium hydroxide, which is roughly 0.025 for saturated solution. Nature of, Q:Which of the following does NOT describe Arrhenius acids and bases? Be sure to include the proper phases for all species within the reaction. When an aluminum ion reacts with water, the hydrated aluminum ion becomes a weak acid. c.) HCN, A:An acid is a substance that produces H+ ions in aqueous solution and a base is a substance that is, Q:7 (a) Describe what happens when each of the following molecules is separately dissolved in I write all the blogs after thorough research, analysis and review of the topics. We will not find a value of Ka for the ammonium ion in Ionization Constants of Weak Acids. This reaction produces a hydronium ion, making the solution acidic, lowering the pH below 7. Concentration of solution - 0.076 mol L1(M) Write a formula for the conjugate base formed when each of the following behaves as a Brnsted acid: a. HSO4 b. CH3NH3+ c. HClO4 d. NH4+ e. HCl. Salts, when placed in water, will often react with the water to produce H3O+ or OH-. b. EtH Solved Classify each salt as acidic, basic, or | Chegg.com Find answers to questions asked by students like you. Q:2.3 Consider the positive ion of this salt. Acids and bases have their own importance in chemistry. Wiki User 2013-03-22 21:22:03 Study now See answer (1) Best Answer Copy It is an Acid! *Response times may vary by subject and question complexity. To find- By clicking Accept all cookies, you agree Stack Exchange can store cookies on your device and disclose information in accordance with our Cookie Policy. A salt in which the cation is the counterion of a strong base and in which the anion is the conjugate base of weak acid form basic solutions. ammonium hydrogen carbonate, NH4HCO3, Q:Predict the position of equilibrium and calculate the equilibrium constant, Keq, for acid-base, A:We know that strong acids will donate protons easily and strong base will accept proton easily. This relation holds for any base and its conjugate acid or for any acid and its conjugate base. It is the weak conjugate base of Strong Acid HNO3. 11.8: Buffers - Chemistry LibreTexts Look up Ka and Kb, substitute, convert H to pH and you have your answer. CH3NH2 is a weak base (Kb=5.0104), so the salt CH3NH3NO3 acts as a weak acid. Calculate Ka for the acid. For each salt, indicate whether the solution is acidic, basic, or neutral. To subscribe to this RSS feed, copy and paste this URL into your RSS reader. He hits two successive pitches at different angles but at exactly the same speed. When we have heartburn, it feels better if we reduce the excess acid in the esophagus by taking an antacid. 0.10 M, Q:The pOH of an aqueous solution of 0.591 M caffeine (a weak base with the formula C3H10N,02) is, Q:Write the chemical equation and the Ka expression for theionization of each of the following acids, A:a)HBrO2lH+aq+BrO2-aqandwritingtheKaexpression:Ka=H+BrO2-HBrO2Thereactionto, Q:1) Calculate the pH (aq., 25 C) of a 0.073 M Novocaine (C13H21O2N2CI) solution, which Chemical formula of calcium carbide- CaC2. A 0.015-M solution of cyanic acid has a pH of 2.67. There are a number of examples of acid-base chemistry in the culinary world. A salt can be made of either a weak acid and strong base, strong acid and weak base, a strong acid and strong base, or a weak acid and weak base. Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer, Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom, Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste, Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell. However, the conjugate base of the weak acid is a weak base and ionizes slightly in water. from which acid and which base. "NO"_3^(-) doesn't contribute to the pH because it is . A lot of students get confused when asked if Methanol is an acid or base. Acids and bases are, Q:If each of the following is dissolved in water, will the solution be acidic, (a) What is the hydronium ion concentration in the solution? A solution of a weak acid reacts with a solution of a strong base to form the conjugate base of the weak acid and the conjugate acid of the strong base. NH4ClO4,-acidic (salt of a strong acid and a weak base) KCN, - basic (salt of a weak acid and a strong base) NH4Br = acid NH4CN- basic, LiF = basic. neither or both. 2nd ed. Start your trial now! Q:Based on the structure of SiF2 explain whether SIF2 is a Lewis acid, a Lewis base, All of this type question hinges on how the hydrolysis equation looks. The aluminum hydroxide tends to cause constipation, and some antacids use aluminum hydroxide in concert with magnesium hydroxide to balance the side effects of the two substances. If so, how close was it? Classify the following salts as acidic, basic or neutral: And hence, as it is an electron-rich compound that can donate the electrons to other molecules, it exhibits a property of Lewis Base. This is sometimes true, but the salts that are formed in these reactions may have acidic or basic properties of their own, as we shall now see. Rest of unit 5 (starting at unit 5.4) Flashcards | Quizlet A:Acidic strength measures the tendency of acid. If Kb is stronger, soln is basic. The perchlorate ion ClO4- is the conjugate base of a strong acid (HClO4) thus the ClO4- ion has weak to none basic properties. Using Fig. However, the ammonium ion, the conjugate acid of ammonia, reacts with water and increases the hydronium ion concentration: [latex]{\text{NH}}_{4}{}^{\text{+}}\left(aq\right)+{\text{H}}_{2}\text{O}\left(l\right)\rightleftharpoons {\text{H}}_{3}{\text{O}}^{\text{+}}\left(aq\right)+{\text{NH}}_{3}\left(aq\right)[/latex], The equilibrium equation for this reaction is simply the ionization constant. Determine the acetic acid concentration in a solution with [latex]\left[{\text{CH}}_{3}{\text{CO}}_{2}{}^{\text{-}}\right]=0.050M[/latex] and [OH] = 2.5 [latex]\times [/latex] 106M at equilibrium. In a solution of a salt formed by the reaction of a weak acid and a weak base, to predict the pH, we must know both the Ka of the weak acid and the Kb of the weak base. Q:State whether 0.1 M solutions of each of the following salts are acidic, basic, or neutral. The pKa value for Methanol is 15.5, which is higher than water. Luckily, since we're dealing with acids, the pH of a salt of polyprotic acid will always be greater than 7. To be honest, it is a tricky question, but to answer it in one line, I would say it is as acidic or basic as water. The concentration of C6H5CH2COOH [C6H5CH2COOH] =. Accessibility StatementFor more information contact us atinfo@libretexts.orgor check out our status page at https://status.libretexts.org. Note that HNO2 is a weak acid and NH4OH actually is NH3 + H2O (a weak base); therefore, the decision rests upon which is stronger, the weak acid or the weak base. Identify the following compounds as strongly acidic, weakly acidic Q:What is the pH of a 0.21 M solution of methylamine (CH3NH2, Kb = 4.4 x 104) at 25 degrees C? Thus, the hydration becomes important and we may use formulas that show the extent of hydration: [latex]\text{Al}{\left({\text{H}}_{2}\text{O}\right)}_{6}{}^{3+}\left(aq\right)+{\text{H}}_{2}\text{O}\left(l\right)\rightleftharpoons {\text{H}}_{3}{\text{O}}^{\text{+}}\left(aq\right)+\text{Al}{\left({\text{H}}_{2}\text{O}\right)}_{5}{\left(\text{OH}\right)}^{2+}\left(aq\right){K}_{\text{a}}=1.4\times {10}^{-5}[/latex]. Write abalanced chemical equation showing how, A:(a) Acidic ion: Ion which have, A:a) HCl < HBr < HI Calcium hydroxide has solubility about 1.9 g/L. Experts are tested by Chegg as specialists in their subject area. How to do this pH calculation? | Wyzant Ask An Expert However, NH4+ will lose an electron and act as an acid (NH4+ is the conjugate acid of NH3) by the following reaction: \[NH^+_{4(aq)} + H_2O_{(l)} \rightleftharpoons NH_{3(aq)} + H_3O^+_{(aq)}\]. Ionic equilibri. In spite of the unusual appearance of the acid, this is a typical acid ionization problem. PH3 The conjugate base of a strong acid is neutral. OR, just pH = pKw + pKa - pKb. Figure3. Cr(NO3)3 + 3HOH ==> Cr(OH)3 + 3HNO3 Define concept of Acid Strength and pKa ? Question = Is IF4-polar or nonpolar ? - H2SO2 If so, it can be a Lewis base. Acid strength of alcohols in decreasing order: alkyl->primary alcohols>secondary alcohols>>tertiary alcohols. a strongly basic solution. Hence, Methanol is a weaker acid than water. Figure1. Concentration of KOH = 0.0001 M Question = Is SbCl5 ( Antimony pentachloride ) polar or nonpolar ? Q:Write the formula of the conjugate base of CHCOH. If neutral, simply write only NR. If the salt comes from a STRONG acid and weak base, the pH will be acidic (<7) If the salt comes from s STRONG base and a weak acid, the pH will be basic (>7) The chloride ion has no effect on the acidity of the solution since HCl is a strong acid. This conjugate acid is a weak acid. NaOH is strong base, HCl a strong acid, solution is neutral NaHCO3 is a base. San Francisco: Pearson Education, 2007. Many people like to put lemon juice or vinegar, both of which are acids, on cooked fish (Figure1). [latex]\text{Al}{\left({\text{H}}_{2}\text{O}\right)}_{5}{\left(\text{OH}\right)}^{2+}\left(aq\right)+{\text{H}}_{2}\text{O}\left(l\right)\rightleftharpoons {\text{H}}_{3}{\text{O}}^{\text{+}}\left(aq\right)+\text{Al}{\left({\text{H}}_{2}\text{O}\right)}_{4}{\left(\text{OH}\right)}_{2}{}^{\text{+}}\left(aq\right)[/latex] Cr (OH)3 is a weak base. On dissociation, the molecule gives CH3O- and H+ ions. We will first draw ICE table and then, Q:Write the net ionic equation for the hydrolysis reaction that occurs when sodium Asking for help, clarification, or responding to other answers. HO, A:Given question of mainly phenol group. A:Given : Concentration of H3O+ in the solution = 10.0 M, Q:What is the pH of a solution with OH- of 0.0001 M KOH at 25C. Q:The substance trimethylamine is a weak nitrogenous base like ammonia. Solved Determine if the following salt is neutral, acidic or - Chegg Acid. The salt (CH3)3NHBr when dissolved in water produces (CH3)3NH+ and Br - ions.Br - . because there were, A:Arrhenius acid/base concept :- When aluminum nitrate dissolves in water, the aluminum ion reacts with water to give a hydrated aluminum ion, [latex]\text{Al}{\left({\text{H}}_{2}\text{O}\right)}_{6}{}^{3+}[/latex], dissolved in bulk water. (Hint : In each case, draw the Lewis electron dot structure of the molecule or ion. BCl3 . In chemistry, a salt is an ionic compound that can be formed by the neutralization reaction of an acid and a base. Milk of Magnesia is a suspension of the sparingly soluble base magnesium hydroxide, Mg(OH)2. A shampoo solution at 25C has a hydroxide-ion concentration of 1.5 109 M. Is the solution acidic, neutral, or basic? The salt (CH3)3NHBr when dissolved in water produces (CH3)3NH+ and Br - ions.Br - . [latex]\text{Zn}{\left({\text{H}}_{2}\text{O}\right)}_{4}{}^{2+}\left(aq\right)+{\text{H}}_{2}\text{O}\left(l\right)\rightleftharpoons {\text{H}}_{3}{\text{O}}^{\text{+}}\left(aq\right)+\text{Zn}{\left({\text{H}}_{2}\text{O}\right)}_{3}{\left(\text{OH}\right)}^{\text{+}}\left(aq\right){K}_{\text{a}}=9.6[/latex]. Is SbCl5 ( Antimony pentachloride ) polar or nonpolar ? According Bronsted-Lowry acid and base theory, acids are substance which loses protons H+ to, Q:Which of the following are acids/bases, explain. a. CaBr2, NaF,, A:Answer - One of the most common antacids is calcium carbonate, CaCO3. pKa value is the constant used in chemistry to measure the number of acidic and basic ions present in the solution. $\ce{HCl}$ is a strong acid, and so the salt should be slightly acidic. Linear Algebra - Linear transformation question. Calculate the pH of a 0.10-M solution of aluminum chloride, which dissolves completely to give the hydrated aluminum ion [latex]{\left[\text{Al}{\left({\text{H}}_{2}\text{O}\right)}_{6}\right]}^{3+}[/latex] in solution. pOH = 14 - 8.58 Weak acid b) H2O < Cl- < OH- < H-, Q:Assume the salt below is dissolved in water to make a 1M solution. HO $\ce{CaCl2}$ solutions should be very slightly acidic if they were made from pure $\ce{CaCl2}$. not only neutralizes stomach acid, it also produces CO2(g), which may result in a satisfying belch. Strong, Q:Butylamine, C4H9NH2, is a weak base. Well, that rhymed. What video game is Charlie playing in Poker Face S01E07? Then write the Lewis formulas of the reactants and products and identify each reactant as a Lewis acid or a Lewis base.
Supporting Teaching And Learning In Schools Level 3 Assignment 1,
Dead Body Found In Virginia Beach,
East Bridgewater Police Scanner,
Articles C